Ceramics composites from iron ore tailings and blast furnace slag

The search for materials and methods capable of reducing human impacts on the environment is of utmost importance nowadays. This study's primary purpose was to analyze the technical feasibility of ceramic composites production utilizing Fundão Dam's Iron Ore Tailings (IOT), Blast Furnace Slag (BFS) from charcoal, and Foundry Sand (FS) as partial substitutes for the traditional raw materials – sand and clay – for application in building industry materials. The composites were molded in rectangular specimens and fired at temperatures of 900, 950, 1000, 1050, and 1200 °C. The developed materials were analyzed and characterized by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), Thermogravimetry (TGA), and Differential Thermal Analysis (DTA). The obtained materials had flexural strength modulus of up to 12.19 MPa, water absorption ranging from 2 to 22%, linear shrinkage ranging from 0.02 to 6.50%, and apparent density ranging from 2.03 to 1.63 g/cm³. The study of the internal structure formation process revealed the formation of amorphous structures in the composites. The results demonstrated that these waste materials may be jointly used in construction materials, contributing to the reduction of natural resource extraction, besides enabling their correct disposal, minimizing environmental impacts, and improving the life quality of the surrounding communities.     

Authenticity green coffee bean species and geographical origin using near-infrared spectroscopy combined with chemometrics

To prevent the adulteration of agricultural resources and provide a solution to enhance the green coffee bean supply chain, authentication using the near-infrared spectroscopy (NIRS) technique was investigated. Partial least square with discrimination analysis (PLS-DA) models combined with various preprocessing methods were built from NIR spectra of 153 Vietnamese green coffee samples. The model combined with the standard normal variate and the first order of derivative yielded excellent performance in predicting coffee species with the error cross-validation of 0.0261. PLS-DA model of mean centre and first-order derivative spectra also yielded good performance in verifying geographical indication of green coffee with the error of 0.0656. By contrast, the predicting abilities of post-harvest methods were poor. The overall results showed a high potential of the NIRS in online authentication practices.     

Strength and deformation properties of frozen sand under a true triaxial stress condition

In recent years, the mechanical properties of frozen soils under complex stress states have attracted significant attention; however, limited by the test apparatus, true triaxial tests on frozen soils have rarely been conducted. To study the strength and deformation properties of frozen sand under a true triaxial stress state, a novel frozen soil testing system, i.e., a true triaxial apparatus, was developed. The apparatus is mainly composed of a temperature control system, a servo host system, a hydraulic servo loading system, and a digital control system. Several true triaxial tests were conducted at a constant minor principal stress (σ₃) and constant intermediate principal stress ratio (b) to study the effect of intermediate principal stress (σ₂) on the mechanical properties of frozen sand. The test results showed that the stress–strain curve can be mainly divided into three stages, with evidence of strain hardening characteristics. The strength, elastic modulus, and friction angle increased with the increase in b from 0 to 0.6, but decreased when increasing b from 0.6 to 1, whereas the cohesion varied little with the variation in b. The deformation in the direction of σ₂ changed from dilative to compressive and that in the direction of σ₃ remained dilative throughout.     

Effect of coral sand powders and seawater salinity on the impact mechanical properties of cemented coral sand

Coral sand is one kind of the important building materials in coral reef engineering practice. The use of cement as a stabilizing agent can significantly improve the mechanical properties of coral sands and is widely applied in the subbase engineering construction in coral reef islands. Cement-stabilized coral sand structures may contain high contents of fine coral particles and salinity because of the high crushability of coral sands and the existence of seawater surrounding them. In this study, the effects of coral sand powders and seawater salinity on the dynamic mechanical properties of cemented coral sand (CCS) were investigated through the split Hopkinson pressure bar (SHPB) tests and Scanning Electron Microscope (SEM) analysis. It was found that the strength (i.e., the peak stress) of CCS specimens increased firstly and then decreased with the increase of powder content. The specimens reached the maximum peak stress when 3% powder content was included. The initial improvement of CCS strength was attributed to the pore-filling effect of coral powders, namely, the micro pores of the CCS specimens could be more effectively filled with higher percentages of coral powders being used in the experiments. However, excessive coral powders resulted in the reduction of specimen strength because these powders could easily be cemented into agglomerates by absorbing water from the specimens. These agglomerates could reduce the cementation strength between the coarse coral particles and the cement. Meanwhile, the peak stress of CCS specimens was found to be negatively correlated with the average strain rate and the ultimate strain. The degree of specimen fracture was found to be correlated with the amount of specific energy absorption during the tests. Furthermore, the “sulfate attack” caused by the inclusion of salinity of water had different influences on the CCS specimens with different coral powder contents. The ettringite and gypsum produced in “sulfate attack” could fill the pores and lead to cracking of the specimens, significantly affecting the specimen strength.     

Role of particle shape on the shear strength of sand-GCL interfaces under dry and wet conditions

Interface shear strength of geosynthetic clay liners (GCL) with the sand particles is predominantly influenced by the surface characteristics of the GCL, size and shape of the sand particles and their interaction mechanisms. This study brings out the quantitative effects of particle shape on the interaction mechanisms and shear strength of GCL-sand interfaces. Interface direct shear tests are conducted on GCL in contact with a natural sand and a manufactured sand of identical gradation, eliminating the particle size effects. Results showed that manufactured sand provides effective particle-fiber interlocking compared to river sand, due to the favorable shape of its grains. Further, the role of particle shape on the hydration of GCL is investigated through interface shear tests on GCL-sand interfaces at different water contents. Bentonite hydration is found to be less in tests with manufactured sand, leading to better interface shear strength. Grain shape parameters of sands, surface changes related to hydration and particle entrapment in GCL are quantified through image analysis on sands and tested GCL surfaces. It is observed that the manufactured sand provides higher interface shear strength and causes lesser hydration related damages to GCL, owing to its angular particles and low permeability.     

Effect of the particle size ratio on macro- and mesoscopic shear characteristics of the geogrid-reinforced rubber and sand mixture interface

As a new type of material for civil engineering projects, the rubber and sand mixture is widely used in roadbed fillers, offering environmental benefits over traditional tyre disposal methods. This study uses a large-scale direct shear apparatus to examine the interface shear properties of the geogrid-reinforced rubber and sand mixture, considering different particle size ratios (r), rubber contents, and normal stresses. Based on indoor tests, direct shear models of the mixture with different values of r are established in PFC^3D, revealing the meso-mechanical mechanism of the mixture in the direct shear process. The results show that when r is greater than 1, incorporating a certain amount of rubber particles can increase the shear strength of the mixture. The r values of 15.78, 7.63, and 3.98 correspond to an optimal rubber content of 30%, 10%, and 20%, respectively. When r is less than 1, mixing rubber particles can only reduce the shear strength of the mixture. When the rubber content is low, the smaller the value of r, the greater is the thickness of the shear band. Furthermore, the normal and tangential contact forces are greater. The fabric anisotropy evolution law of the mixture is consistent with the change in the contact force distribution.     

Green Measurements for Software Product Based on Sustainability Dimensions

Software is a central component in the modern world and vastly affects the environment’s sustainability. The demand for energy and resource requirements is rising when producing hardware and software units. Literature study reveals that many studies focused on green hardware; however, limited efforts were made in the greenness of software products. Green software products are necessary to solve the issues and problems related to the long-term use of software, especially from a sustainability perspective. Without a proper mechanism for measuring the greenness of a particular software product executed in a specific environment, the mentioned benefits will not be attained. Currently, there are not enough works to address this problem, and the green status of software products is uncertain and unsure. This paper aims to identify the green measurements based on sustainable dimensions in a software product. The second objective is to reveal the relationships between the elements and measurements through empirical study. The study is conducted in two phases. The first phase is the theoretical phase, where the main components, measurements and practices that influence the sustainability of a software product are identified. The second phase is the empirical study that involved 103 respondents in Malaysia investigating current practices of green software in the industrial environment and further identifying the main sustainability dimensions and measurements and their impact on achieving green software products. This study has revealed seven green measurements of software product: Productivity, Usability, Cost Reduction, Employee Support, Energy Efficiency, Resource Efficiency and Tool Support. The relationships are statistically significant, with a significance level of less than 0.01 (p = 0.000). Thus, the hypothesised relationships were all accepted. The contributions of this study revolve around the research perspectives of the measurements to attain a green software product.     

Photocatalytic performance of β-Ga2O3 microcubes towards efficient degradation of malachite green

In this work, the photocatalytic degradation of malachite green (MG) solutions by β-Ga₂O₃ was investigated. The latter was synthetized by reacting gallium nitrate with concentrated formic acid, which produced gallium formate. The thermal decomposition of this compound at 850 °C produced single-phase β-Ga₂O₃. The resulting morphology corresponds to non-agglomerated microcubes, with a size in the range of 0.8 and 2.3 μm. The surface chemical composition and bandgap energy of this oxide were determined by X-ray photoelectron spectroscopy (XPS) and the Tauc method, respectively. The photodegradation of MG was carried out under violet light (λ = 405 nm), at room temperature, using the as-prepared powder. The results revealed a fast degradation of the dye during the first 20 min, which attenuates over time. The rate of photodegradation depends on the amount of β-Ga₂O₃ used and can be fitted by an exponential equation. The role of free hydroxyl radicals and reactive oxygen species in photocatalysis was addressed by using analytic techniques (FTIR and XPS).     

Contribution of Drugs Interfering with Protein and Cell Wall Synthesis to the Persistence of Pseudomonas aeruginosa Biofilms: An In Vitro Model

The occurrence of Pseudomonas aeruginosa (PA) persisters, including viable but non-culturable (VBNC) forms, subpopulations of tolerant cells that can survive high antibiotic doses, is the main reason for PA lung infections failed eradication and recurrence in Cystic Fibrosis (CF) patients, subjected to life-long, cyclic antibiotic treatments. In this paper, we investigated the role of subinhibitory concentrations of different anti-pseudomonas antibiotics in the maintenance of persistent (including VBNC) PA cells in in vitro biofilms. Persisters were firstly selected by exposure to high doses of antibiotics and their abundance over time evaluated, using a combination of cultural, qPCR and flow cytometry assays. Two engineered GFP-producing PA strains were used. The obtained results demonstrated a major involvement of tobramycin and bacterial cell wall-targeting antibiotics in the resilience to starvation of VBNC forms, while the presence of ciprofloxacin and ceftazidime/avibactam lead to their complete loss. Moreover, a positive correlation between tobramycin exposure, biofilm production and c-di-GMP levels was observed. The presented data could allow a deeper understanding of bacterial population dynamics during the treatment of recurrent PA infections and provide a reliable evaluation of the real efficacy of the antibiotic treatments against the bacterial population within the CF lung.